FR 6814 then QR 152 at Madrid
Manchester → Madrid → Doha
Timetable, Madrid time
23:55FR 6814 from Manchester at the gate
22:05QR 152 to Doha leaves the gate
22 h 10 apart on the timetable, overnight
QR 152 leaves 22 h 10 after FR 6814 arrives on the timetable: more than half a day, so not a connection we count.