FR 7466 then FR 5301 at Madrid
Tangier → Madrid → Luxembourg
Timetable, Madrid time
14:05FR 7466 from Tangier at the gate
07:15FR 5301 to Luxembourg leaves the gate
17 h 10 apart on the timetable, overnight
FR 5301 leaves 17 h 10 after FR 7466 arrives on the timetable: more than half a day, so not a connection we count.