FR 7466 then IB 191 at Madrid
Tangier → Madrid → Caracas
Timetable, Madrid time
14:05FR 7466 from Tangier at the gate
13:10IB 191 to Caracas leaves the gate
23 h 05 apart on the timetable, overnight
IB 191 leaves 23 h 05 after FR 7466 arrives on the timetable: more than half a day, so not a connection we count.