FR 7466 then PU 701 at Madrid
Tangier → Madrid → Caracas
Timetable, Madrid time
14:05FR 7466 from Tangier at the gate
13:00PU 701 to Caracas leaves the gate
22 h 55 apart on the timetable, overnight
PU 701 leaves 22 h 55 after FR 7466 arrives on the timetable: more than half a day, so not a connection we count.