FR 9471 then FR 4273 at Madrid
Pisa → Madrid → Tirana
Timetable, Madrid time
17:25FR 9471 from Pisa at the gate
13:40FR 4273 to Tirana leaves the gate
20 h 15 apart on the timetable, overnight
FR 4273 leaves 20 h 15 after FR 9471 arrives on the timetable: more than half a day, so not a connection we count.