FR 9471 then FR 9150 at Madrid
Pisa → Madrid → Vienna
Timetable, Madrid time
17:25FR 9471 from Pisa at the gate
14:45FR 9150 to Vienna leaves the gate
21 h 20 apart on the timetable, overnight
FR 9150 leaves 21 h 20 after FR 9471 arrives on the timetable: more than half a day, so not a connection we count.