FR 9471 then W4 3562 at Madrid
Pisa → Madrid → Timisoara
Timetable, Madrid time
20:00FR 9471 from Pisa at the gate
19:30W4 3562 to Timisoara leaves the gate
23 h 30 apart on the timetable, overnight
W4 3562 leaves 23 h 30 after FR 9471 arrives on the timetable: more than half a day, so not a connection we count.