FR 9471 then W4 5152 at Madrid
Pisa → Madrid → Tirana
Timetable, Madrid time
18:20FR 9471 from Pisa at the gate
16:50W4 5152 to Tirana leaves the gate
22 h 30 apart on the timetable, overnight
W4 5152 leaves 22 h 30 after FR 9471 arrives on the timetable: more than half a day, so not a connection we count.