FR 9601 then 2W 3503 at Madrid
Rome → Madrid → Punta Cana
Timetable, Madrid time
19:10FR 9601 from Rome at the gate
14:552W 3503 to Punta Cana leaves the gatealso 2W 3505
19 h 45 apart on the timetable, overnight
2W 3503 leaves 19 h 45 after FR 9601 arrives on the timetable: more than half a day, so not a connection we count.