FR 9601 then W4 5152 at Madrid
Rome → Madrid → Tirana
Timetable, Madrid time
19:50FR 9601 from Rome at the gate
16:50W4 5152 to Tirana leaves the gate
21 h apart on the timetable, overnight
W4 5152 leaves 21 h after FR 9601 arrives on the timetable: more than half a day, so not a connection we count.