IB 1402 then AR 1133 at Madrid
Valencia → Madrid → Buenos Aires
Timetable, Madrid time
01:35IB 1402 from Valencia at the gate
22:15AR 1133 to Buenos Aires leaves the gate
20 h 40 apart on the timetable
AR 1133 leaves 20 h 40 after IB 1402 arrives on the timetable: more than half a day, so not a connection we count.