IB 1402 then W4 6314 at Madrid
Valencia → Madrid → Milan
Timetable, Madrid time
01:35IB 1402 from Valencia at the gate
23:10W4 6314 to Milan leaves the gate
21 h 35 apart on the timetable
W4 6314 leaves 21 h 35 after IB 1402 arrives on the timetable: more than half a day, so not a connection we count.