IB 194 then FR 3186 at Madrid
Caracas → Madrid → Manchester
Timetable, Madrid time
09:15IB 194 from Caracas at the gate
06:30FR 3186 to Manchester leaves the gate
21 h 15 apart on the timetable, overnight
FR 3186 leaves 21 h 15 after IB 194 arrives on the timetable: more than half a day, so not a connection we count.