IB 194 then W4 6314 at Madrid
Caracas → Madrid → Milan
Timetable, Madrid time
09:15IB 194 from Caracas at the gate
23:10W4 6314 to Milan leaves the gate
13 h 55 apart on the timetable
W4 6314 leaves 13 h 55 after IB 194 arrives on the timetable: more than half a day, so not a connection we count.