IB 672 then FR 4066 at Madrid
Milan → Madrid → Catania
Timetable, Madrid time
12:50IB 672 from Milan at the gatealso VY 5277, LA 5422, QR 6520, AA 8662
07:00FR 4066 to Catania leaves the gate
18 h 10 apart on the timetable, overnight
FR 4066 leaves 18 h 10 after IB 672 arrives on the timetable: more than half a day, so not a connection we count.