IB 782 then FR 4066 at Madrid
Berlin → Madrid → Catania
Timetable, Madrid time
14:50IB 782 from Berlin at the gatealso VY 5083, AA 8506
07:00FR 4066 to Catania leaves the gate
16 h 10 apart on the timetable, overnight
FR 4066 leaves 16 h 10 after IB 782 arrives on the timetable: more than half a day, so not a connection we count.