LA 1523 then W4 6314 at Madrid
Vigo → Madrid → Milan
Timetable, Madrid time
10:30LA 1523 from Vigo at the gatealso VY 5156, AT 5433, PC 7866
23:10W4 6314 to Milan leaves the gate
12 h 40 apart on the timetable
W4 6314 leaves 12 h 40 after LA 1523 arrives on the timetable: more than half a day, so not a connection we count.