LH 2602 then FR 1206 at Madrid
Munich → Madrid → Venezia
Timetable, Madrid time
14:00LH 2602 from Munich at the gate
09:30FR 1206 to Venezia leaves the gate
19 h 30 apart on the timetable, overnight
FR 1206 leaves 19 h 30 after LH 2602 arrives on the timetable: more than half a day, so not a connection we count.