OB 776 then FR 1206 at Madrid
Santa Cruz → Madrid → Venezia
Timetable, Madrid time
12:15OB 776 from Santa Cruz at the gate
09:40FR 1206 to Venezia leaves the gate
21 h 25 apart on the timetable, overnight
FR 1206 leaves 21 h 25 after OB 776 arrives on the timetable: more than half a day, so not a connection we count.