PU 302 then FR 1206 at Madrid
Lima → Madrid → Venezia
Timetable, Madrid time
12:45PU 302 from Lima at the gate
09:40FR 1206 to Venezia leaves the gate
20 h 55 apart on the timetable, overnight
FR 1206 leaves 20 h 55 after PU 302 arrives on the timetable: more than half a day, so not a connection we count.