PU 302 then W4 6460 at Madrid
Lima → Madrid → Milan
Timetable, Madrid time
15:20PU 302 from Lima at the gate
13:00W4 6460 to Milan leaves the gate
21 h 40 apart on the timetable, overnight
W4 6460 leaves 21 h 40 after PU 302 arrives on the timetable: more than half a day, so not a connection we count.