PU 702 then AA 8855 at Madrid
Caracas → Madrid → Almeria
Timetable, Madrid time
10:00PU 702 from Caracas at the gate
07:35AA 8855 to Almeria leaves the gate
21 h 35 apart on the timetable, overnight
AA 8855 leaves 21 h 35 after PU 702 arrives on the timetable: more than half a day, so not a connection we count.