PU 702 then FR 3009 at Madrid
Caracas → Madrid → Milan
Timetable, Madrid time
10:00PU 702 from Caracas at the gate
09:15FR 3009 to Milan leaves the gate
23 h 15 apart on the timetable, overnight
FR 3009 leaves 23 h 15 after PU 702 arrives on the timetable: more than half a day, so not a connection we count.