PU 702 then FR 3186 at Madrid
Caracas → Madrid → Manchester
Timetable, Madrid time
10:00PU 702 from Caracas at the gate
06:00FR 3186 to Manchester leaves the gate
20 h apart on the timetable, overnight
FR 3186 leaves 20 h after PU 702 arrives on the timetable: more than half a day, so not a connection we count.