PU 702 then FR 3876 at Madrid
Caracas → Madrid → Tangier
Timetable, Madrid time
10:00PU 702 from Caracas at the gate
06:10FR 3876 to Tangier leaves the gate
20 h 10 apart on the timetable, overnight
FR 3876 leaves 20 h 10 after PU 702 arrives on the timetable: more than half a day, so not a connection we count.