PU 702 then W4 7543 at Madrid
Caracas → Madrid → Seville
Timetable, Madrid time
10:00PU 702 from Caracas at the gate
09:40W4 7543 to Seville leaves the gate
23 h 40 apart on the timetable, overnight
W4 7543 leaves 23 h 40 after PU 702 arrives on the timetable: more than half a day, so not a connection we count.