SK 581 then FR 5376 at Madrid
Copenhagen → Madrid → Brussels Charleroi
Timetable, Madrid time
12:00SK 581 from Copenhagen at the gate
09:20FR 5376 to Brussels Charleroi leaves the gate
21 h 20 apart on the timetable, overnight
FR 5376 leaves 21 h 20 after SK 581 arrives on the timetable: more than half a day, so not a connection we count.