TP 1014 then FR 4066 at Madrid
Lisbon → Madrid → Catania
Timetable, Madrid time
14:05TP 1014 from Lisbon at the gate
07:00FR 4066 to Catania leaves the gate
16 h 55 apart on the timetable, overnight
FR 4066 leaves 16 h 55 after TP 1014 arrives on the timetable: more than half a day, so not a connection we count.