U2 3209 then FR 5997 at Madrid
Edinburgh → Madrid → London Stansted
Timetable, Madrid time
20:05U2 3209 from Edinburgh at the gate
18:55FR 5997 to London Stansted leaves the gate
22 h 50 apart on the timetable, overnight
FR 5997 leaves 22 h 50 after U2 3209 arrives on the timetable: more than half a day, so not a connection we count.