UA 260 then FR 3831 at Madrid
Washington → Madrid → Bologna
Timetable, Madrid time
07:45UA 260 from Washington at the gatealso AC 3816, SN 8927, LH 9385
21:00FR 3831 to Bologna leaves the gate
13 h 15 apart on the timetable
FR 3831 leaves 13 h 15 after UA 260 arrives on the timetable: more than half a day, so not a connection we count.