UX 1040 then FR 4066 at Madrid
Rome → Madrid → Catania
Timetable, Madrid time
13:05UX 1040 from Rome at the gatealso ET 1424, EY 4333, AM 6926, AZ 7116, AD 7897
09:30FR 4066 to Catania leaves the gate
20 h 25 apart on the timetable, overnight
FR 4066 leaves 20 h 25 after UX 1040 arrives on the timetable: more than half a day, so not a connection we count.