UX 1082 then FR 4066 at Madrid
Venezia → Madrid → Catania
Timetable, Madrid time
13:05UX 1082 from Venezia at the gatealso MU 4983
09:30FR 4066 to Catania leaves the gate
20 h 25 apart on the timetable, overnight
FR 4066 leaves 20 h 25 after UX 1082 arrives on the timetable: more than half a day, so not a connection we count.