UX 138 then FR 9602 at Madrid
Quito → Madrid → Rome
Timetable, Madrid time
05:00UX 138 from Quito at the gate
19:45FR 9602 to Rome leaves the gate
14 h 45 apart on the timetable
FR 9602 leaves 14 h 45 after UX 138 arrives on the timetable: more than half a day, so not a connection we count.