UX 1516 then FR 2436 at Madrid
Munich → Madrid → Rome
Timetable, Madrid time
13:35UX 1516 from Munich at the gate
09:35FR 2436 to Rome leaves the gate
20 h apart on the timetable, overnight
FR 2436 leaves 20 h after UX 1516 arrives on the timetable: more than half a day, so not a connection we count.