UX 72 then FR 494 at Madrid
Caracas → Madrid → Dublin
Timetable, Madrid time
12:35UX 72 from Caracas at the gate
07:50FR 494 to Dublin leaves the gate
19 h 15 apart on the timetable, overnight
FR 494 leaves 19 h 15 after UX 72 arrives on the timetable: more than half a day, so not a connection we count.