VL 1806 then IB 107 at Madrid
Munich → Madrid → Buenos Aires
Timetable, Madrid time
23:35VL 1806 from Munich at the gate
12:20IB 107 to Buenos Aires leaves the gate
12 h 45 apart on the timetable, overnight
IB 107 leaves 12 h 45 after VL 1806 arrives on the timetable: more than half a day, so not a connection we count.