VY 1006 then IB 545 at Madrid
Barcelona → Madrid → Porto
Timetable, Madrid time
11:35VY 1006 from Barcelona at the gatealso QR 5524, IB 5990, LL 5990
11:25IB 545 to Porto leaves the gatealso CX 1867, VY 5306, DT 6092, QR 6930, AA 8665
23 h 50 apart on the timetable, overnight
IB 545 leaves 23 h 50 after VY 1006 arrives on the timetable: more than half a day, so not a connection we count.