VY 1010 then FR 1206 at Madrid
Barcelona → Madrid → Venezia
Timetable, Madrid time
09:45VY 1010 from Barcelona at the gate
22:25FR 1206 to Venezia leaves the gate
12 h 40 apart on the timetable
FR 1206 leaves 12 h 40 after VY 1010 arrives on the timetable: more than half a day, so not a connection we count.