W4 6013 then W4 5152 at Madrid
Rome → Madrid → Tirana
Timetable, Madrid time
19:55W4 6013 from Rome at the gate
16:50W4 5152 to Tirana leaves the gate
20 h 55 apart on the timetable, overnight
W4 5152 leaves 20 h 55 after W4 6013 arrives on the timetable: more than half a day, so not a connection we count.