W4 6313 then TP 1021 at Madrid
Milan → Madrid → Lisbon
Timetable, Madrid time
22:25W4 6313 from Milan at the gate
21:10TP 1021 to Lisbon leaves the gate
22 h 45 apart on the timetable, overnight
TP 1021 leaves 22 h 45 after W4 6313 arrives on the timetable: more than half a day, so not a connection we count.