W4 6729 then FR 498 at Madrid
Venezia → Madrid → London Stansted
Timetable, Madrid time
08:40W4 6729 from Venezia at the gate
06:25FR 498 to London Stansted leaves the gate
21 h 45 apart on the timetable, overnight
FR 498 leaves 21 h 45 after W4 6729 arrives on the timetable: more than half a day, so not a connection we count.