W4 6729 then FR 5376 at Madrid
Venezia → Madrid → Brussels Charleroi
Timetable, Madrid time
08:40W4 6729 from Venezia at the gate
07:10FR 5376 to Brussels Charleroi leaves the gate
22 h 30 apart on the timetable, overnight
FR 5376 leaves 22 h 30 after W4 6729 arrives on the timetable: more than half a day, so not a connection we count.