EC 5521 then FR 3204 at Manchester
Alicante → Manchester → Roma
Timetable, Manchester time
08:30EC 5521 from Alicante at the gate
07:40FR 3204 to Roma leaves the gate
23 h 10 apart on the timetable, overnight
FR 3204 leaves 23 h 10 after EC 5521 arrives on the timetable: more than half a day, so not a connection we count.