EC 5521 then FR 6814 at Manchester
Alicante → Manchester → Madrid
Timetable, Manchester time
08:30EC 5521 from Alicante at the gate
08:15FR 6814 to Madrid leaves the gate
23 h 45 apart on the timetable, overnight
FR 6814 leaves 23 h 45 after EC 5521 arrives on the timetable: more than half a day, so not a connection we count.