EC 7001 then FR 5624 at Manchester
Málaga → Manchester → Pisa
Timetable, Manchester time
19:40EC 7001 from Málaga at the gate
16:30FR 5624 to Pisa leaves the gate
20 h 50 apart on the timetable, overnight
FR 5624 leaves 20 h 50 after EC 7001 arrives on the timetable: more than half a day, so not a connection we count.