EC 7501 then FR 7542 at Manchester
Faro → Manchester → Barcelona
Timetable, Manchester time
09:15EC 7501 from Faro at the gate
07:40FR 7542 to Barcelona leaves the gate
22 h 25 apart on the timetable, overnight
FR 7542 leaves 22 h 25 after EC 7501 arrives on the timetable: more than half a day, so not a connection we count.