FR 3186 then FR 6630 at Manchester
Madrid → Manchester → Cologne
Timetable, Manchester time
11:55FR 3186 from Madrid at the gate
10:45FR 6630 to Cologne leaves the gate
22 h 50 apart on the timetable, overnight
FR 6630 leaves 22 h 50 after FR 3186 arrives on the timetable: more than half a day, so not a connection we count.