FR 3209 then FR 5624 at Manchester
Málaga → Manchester → Pisa
Timetable, Manchester time
22:45FR 3209 from Málaga at the gate
20:25FR 5624 to Pisa leaves the gate
21 h 40 apart on the timetable, overnight
FR 5624 leaves 21 h 40 after FR 3209 arrives on the timetable: more than half a day, so not a connection we count.