FR 3223 then FR 6596 at Manchester
Brussels Charleroi → Manchester → Barcelona
Timetable, Manchester time
07:30FR 3223 from Brussels Charleroi at the gate
20:15FR 6596 to Barcelona leaves the gate
12 h 45 apart on the timetable
FR 6596 leaves 12 h 45 after FR 3223 arrives on the timetable: more than half a day, so not a connection we count.