FR 3223 then FR 6814 at Manchester
Brussels Charleroi → Manchester → Madrid
Timetable, Manchester time
16:15FR 3223 from Brussels Charleroi at the gate
12:50FR 6814 to Madrid leaves the gate
20 h 35 apart on the timetable, overnight
FR 6814 leaves 20 h 35 after FR 3223 arrives on the timetable: more than half a day, so not a connection we count.